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Olivia Palermo added a new gig to her quickly-expanding modeling resume: Tibi’s poster girl. The former star of MTV’s The City recently posed for the brand’s spring 2011 lookbook, wearing Tibi pieces mixed with piles of accessories from her own closet. See Palermo model Tibi’s ruffled trench coats, gauzy gowns, animal print minis, and more in the gallery.

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• Olivia Palermo: Designer?
• Olivia Palermo Models for Mango!

It was only a matter of time before sexy socialite and The City star Olivia Palermo transitioned to modeling. In addition to being the face of Hogan, Olivia is featured in the new Mango catalog with her incredibly handsome boyfriend Johannes Huebl. “We enjoy working together,” Olivia told Mango, “and I think photographers love to see the chemistry.” We do, too!

It’s only been a year and a half since Whitney Port first arrived in New York with the dream of becoming a fashion designer, but The City star has managed to live her dream.  In the show’s second season (premiering tonight on MTV at 10:30p.m. EST/PST), we’ll get to see Port’s journey to the runway with her line Whitney Eve. We chatted with the reality star, who dished about her fashion inspirations and the lessons she’s learned in front of the cameras.

InStyle.com: What can we expect from tonight’s season premiere?

Whitney Port: The premiere episode starts with me showing my line at Bryant Park last fall. It was a group show and it was all about gearing up for that. It was very intense and surreal. It happens so fast that you kind of black out after. It was one of the most exciting things I’ve ever experienced.

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