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Angelina Jolie celebrated her directorial debut with beau Brad Pitt (in Dolce & Gabbana) at the Berlin premiere of her film, In the Land of Blood and Honey. She chose a long sleeved Jenny Packham gown for the occasion, and accessorized with Vhernier jewels. “It’s pretty exciting,” Packham told InStyle.com of having Jolie in her design at her fall 2012 runway show during New York Fashion Week. “She likes a quite classic look, and the dress gave her that.” Agreed! See more stars at last weekend’s hottest parties in the gallery.

— Leah Abrahams, reporting by Nakisha Williams

While Gwen Stefani wasn’t in New York herself to reveal her latest lineup for L.A.M.B. at Fashion Week, the collection spoke for her—it was everything Gwen in a loud way. Neon yellows shot through retro punk looks, flirty mini skirts paired with boyish blazers, and digital prints covered her signature jumpsuits. The accessories—always big-sellers—included chunky platform heels and boots, bright bags, and cat-eye sunglasses. It’s obvious the SoCal rock star would wear every single one of these looks. But the bigger question is: Would you? See our favorite looks from the collection in the gallery!

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— Violet Gaynor

Rachel Zoe looked to rock and roll and ’60s glam to inspire her fall collection, which she showed during New York Fashion Week yesterday. “I was inspired by London street style fashion,” the designer told us backstage after the show. “The Rolling Stones, Marianne Faithfull, The Beatles—put that into a modern day woman and there you have it!” The result: Slim suits in textured tweeds and velvets, topped off with shaggy fur jackets. Her accessories and outerwear featured faux and real fur vests, head wraps and hats, while her Art Deco-inspired costume jewelry shone against Mick Jagger-worthy suits and sequined dresses. Click through the gallery to see our favorite looks from the show!

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— Randy Miller and Caitlin Petreycik