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How is Charlize Theron getting ready to present at Sunday’s Academy Awards? “This is how I’m getting ready, start with the heart,” the actress told InStyle.com during a private dinner at the recently-opened TOMS flagship store in Venice. During the height of Oscars weekend, together with TOMS Shoes founder Blake Mycoskie, the pair celebrated the launch of the third collaboration between the charitable shoe brand (for each pair bought, one is given to a child in need) and the Charlize Theron Africa Outreach Project (CTAOP), which focuses on keeping African youth safe from HIV/AIDS. “Blake, I’m not ever going to get married, but this is the closest I’m going to get to a marriage that actually works,” Theron joked. “Your team and your long-term commitment to us has been so amazing.” And their collaboration expanded: For the third go-around of the limited-edition footwear (in stores and toms.com next month), they created another women’s shoe, and a matching child pair, too—a natural evolution given that Theron’s son Jackson, loves to wear TOMS and the recently-married Mycoskie is planning to expand his family soon. “I think I have every style of TOMS that my son is wearing, yes, and he has these,” she said of the new style, which features the sun-inspired white and yellow CTAOP logo and the organization’s motto, Reach Out, Think Beyond, and Look Within scrawled inside. Theron credits her team for the design; for her, it’s all about the heart of the issue: “There is nothing that moves me as much as having these crates of shoes show up at schools in the middle of nowhere,” Theron said. “I invite anyone to come and try not to be emotional about it. It really is incredible.”

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This Sunday, the 85th Academy Awards ceremony will include a special tribute to James Bond in honor of the film series’ 50th anniversary! But before Adele hits the stage to perform her nominated title tune from Skyfall, the most recent “007″ film, alongside fellow franchise vocalist Shirley Bassey (she performed three Bond themes), we’re taking a look back at the 23 Bond beauties who have dazzled us on the silver screen over the past 50 years. Click through the gallery to see every Bond girl, from Skyfall‘s Bérénice Marlohe to the first one ever, Honey Ryder. And here’s to 50 more years!

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Adele will sing live at the Oscars! Following some speculation leading up to her presence at the Golden Globes last week, the Academy has confirmed that she will indeed grace the stage for a live performance at the 85th Annual Academy Awards. “It’s an honor to be nominated and terrifyingly wonderful to be singing in front of people who have captured my imagination over and over again,” Adele said in a statement. “It’s something I’ve never experienced and probably only ever will once!“ The British singer will belt out the song she penned as the title track for Skyfall, which is also nominated in the Best Original Song category. We can’t wait to hear her sing again—this will be her first live performance since giving birth to her son in October. Tune in to ABC February 24 at 7/6c to see it!

Plus, see this year’s Oscar nominees!

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