Ready for some of the year’s biggest red carpet moments at the Cannes Film Festival? With the 2014 festivities kicking off today, we’re taking a look back at some of the most iconic and unforgettable looks to grace the red carpet of festival’s past.

From Jessica Biel’s stunning serpent-adorned Marchesa creation in 2013 to Angelina Jolie’s sweeping Emanuel Ungaro canary yellow gown in 2007 and Sharon Stone’s peek-a-boo Valentino from 1995, the Cannes Film Festival has produced some of the most memorable red carpet looks of all time. One of our tops picks? Eva Longoria’s wow-worthy Marchesa gown from the festival’s 2012 opening ceremony, which featured intricate embroidered details and a breath-taking tulle train that shut down the red carpet.

Want more from Cannes? See the most memorable looks to touch down in the French Riviera in our gallery!