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Burberry Prorsum presented their Spring 2010 collection in London this season (they typically show in Milan) in honor of London Fashion Week’s 25th anniversary—and the stars came out to celebrate! Victoria Beckham posed for the cameras while Mary-Kate Olsen perched next to Alexa Chung and Freida Pinto and Emma Watson looked on alongside Gwyneth Paltrow.

See more stars at London Fashion Week and visit InStyle.com daily for runway and front row coverage during the Milan and Paris shows.

Drew Barrymore knows there is a first time for everything. As she makes her big-time directing debut (with Whip It, out October 2nd), she dished to InStyle on more of her firsts, from broken hearts to fashion regrets! While Barrymoore’s looks have changed through the years, we think her style is pretty flawless. Try on her cover girl hair style now and for more exclusives, check out the October issue of InStyle, on newsstands this week.

Burberry Prorsum‘s runway show was all glitz and glam, in part due to the star-studded front row, but mostly because it featured one of our favorite trends: metallic sequins! Even Emma Watson—who is stars in the label’s ad campaign—worked some major sparkle at the show in a gold sequin minidress. But don’t save your sequins for the holidays; wear a sparkly jacket now with jeans and sleek boots for a glamorous fall look.

3.1 Phillip Lim Coat, $1,500; visit net-a-porter.com.

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You don’t have to be a French actress to rock gorgeous cat-eye makeup—which celebs like Rihanna, Angelina Jolie and Zoe Saldana know very well. The key to getting this sultry, edgy look? A steady hand and a thin, heavily pigmented liquid liner, like the new NARS Eyeliner Stylo ($27). Available in three shades, the marker-style tip gives us grade school flashbacks, but the silky, flawless results are anything but juvenile. Meow, indeed.

Thanks to the likes of So You Think You Can Dance‘s Cat Deeley and Glee‘s Lea Michele, Wednesday is quickly becoming the night for must-see TV—and now you have a chance to join in on the fun, in person! Enter now for the chance to win a trip for two to Los Angeles, where you would be escorted by a cast member from Glee to the live finale of SYTYCD. Catch both shows back-to-back tonight starting at 8pm EST on FOX.

Need outfit inspiration? Check out more of Cat Deeley’s enviable style.